When your diver ascends too soon, the new quick tension transform causes small bubbles out-of Letter
where C ‘s the concentration of mixed energy on harmony, P is the partial stress of the fuel, and you will k is the Henry’s law ongoing, hence should be computed experimentally per combination of gasoline, solvent, and you can temperature. The newest systems of the Henry’s laws lingering are thus mol/(L·automatic teller machine) = M/atm. Opinions of your own Henry’s laws constants to have choices of numerous fumes in water within 20°C is actually placed in Desk 1step 3.6 «Henry’s Rules Constants to own Chose Smoke in water at 20°C».
As the data in Table 13.6 «Henry’s Law Constants for Selected Gases in Water at 20°C» demonstrate, the concentration of a dissolved gas in water at a given pressure depends strongly on its physical properties. For a series of related substances, London dispersion forces increase as molecular mass increases. Thus among the elements of group 18, the Henry’s law constants increase smoothly from He to Ne to Ar. The table also shows that O2 is almost twice as soluble as N2. Although London dispersion forces are too weak to explain such a large difference, O2 is paramagnetic and hence more polarizable than N2, which explains its high solubility.
Gases that react chemically with water, such as HCl and the other hydrogen halides, H2S, and NH3, do not obey Henry’s law; all of these gases are much more soluble than predicted by Henry’s law. For example, HCl reacts with water to give H + (aq) and Cl ? (aq), not dissolved HCl molecules, and its dissociation into ions results in a much higher solubility than expected for a neutral molecule.
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Henry’s law has important applications. For example, bubbles of CO2 form as soon as a carbonated beverage is opened because the drink was bottled under CO2 at a pressure greater than 1 atm. When the bottle is opened, the pressure of CO2 above the solution drops rapidly, and some of the dissolved gas escapes from the solution as bubbles. Henry’s law also explains why scuba divers have to be careful to ascend to the surface slowly after a dive if they are breathing compressed air. At the higher pressures under water, more N2 from the air dissolves in the diver’s internal fluids. 2 to form throughout the body, a condition known as “the bends.” These bubbles can block the flow of blood through the small blood vessels, causing great pain and even proving fatal in some cases.
Due to the low Henry’s law constant for O2 in water, the levels of dissolved oxygen in water are too low to support the energy needs of multicellular organisms, including humans. To increase the O2 concentration in internal fluids, organisms synthesize highly soluble carrier molecules that bind O2 reversibly. For example, human red blood cells contain a protein called hemoglobin that specifically binds O2 and facilitates its transport from the lungs to the tissues, where it is used to oxidize food molecules to provide energy. The concentration of hemoglobin in normal blood is about 2.2 mM, and each hemoglobin molecule can bind four O2 molecules. Although the concentration of dissolved O2 in blood serum at 37°C (normal body temperature) is only 0.010 mM, the total dissolved O2 concentration is 8.8 mM, almost a thousand times greater than would be possible without hemoglobin. Synthetic oxygen carriers based on fluorinated alkanes have been developed for use as an emergency replacement for whole blood. Unlike donated blood, these “blood substitutes” do not require refrigeration and have a long shelf life. Their very high Henry’s law constants for O2 result in hitch hesap silme dissolved oxygen concentrations comparable to those in normal blood.